Published November 2019 | Version v1
Journal article

Suggestion for a Search of Diisocyanomethane (CNCH2NC) in the Cosmic Objects: Potential Spectral Lines

Creators

  • 1. Amity University, Amity Centre for Astronomy & Astrophysics, Amity Institute of Applied Sciences (India)

Description

Finding several molecules having cyanide group (-C≡N) and isocyanide group (-N≡C), scientists searching for life in the universe, are interested in the molecules having two cyanide or isocyanide groups. Diisocyanomethane (CNCH2NC) having two isocyano groups is an interesting candidate for the astronomers, though it has not been detected in any cosmic object. However, three organic isocyanides (HNC, CH3NC, HCCNC) have been found in the interstellar medium (ISM). Submillimeter wave spectrum of CNCH2NC is analyzed by spectroscopists, so that it could be searched in the ISM. For searching CNCH2NC in a cosmic object, information about its strong spectral lines is essentially required. For that, in our investigation, the rotational levels of CNCH2NC can be classified into two species. The energies of lower 250 rotational levels up to 108 cm−1, in the ground vibrational state, and the radiative transition probabilities for rotational transitions in each species are calculated, using the values of rotational and centrifugal distortion constants along with the electric dipole moment. A set of statistical equilibrium equations coupled with the equations of radiative transfer is solved by using the radiative transition probabilities and the scaled values of collisional rate coefficients as input data. For each species, we have found two transitions showing emission feature and four transitions showing anomalous absorption. These 12 transitions may help in the detection of CNCH2NC in a cosmic object.

Additional details

Identifiers

Publishing Information

Journal Title
Astronomy Reports (Print)
Journal Volume
63
Journal Issue
11
Journal Page Range
p. 963-969
ISSN
1063-7729

INIS

Country of Publication
Russian Federation
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54074075
Subject category
S79: ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ABSORPTION; ELECTRIC DIPOLE MOMENTS; EQUILIBRIUM; MOLECULES; RADIANT HEAT TRANSFER; SPECTRA; UNIVERSE; VIBRATIONAL STATES
Descriptors DEC
DIPOLE MOMENTS; ELECTRIC MOMENTS; ENERGY LEVELS; ENERGY TRANSFER; EXCITED STATES; HEAT TRANSFER; SORPTION

Optional Information

Copyright
Copyright (c) 2019 Pleiades Publishing, Ltd.