Sign system choice influence on the substance formation forecast in A2MoO4-B2(MoO4)3 and A2MoO4-CMoO4 systems
- 1. AN SSSR, Ulan-Ude. Inst. Estestvennykh Nauk
Description
Three sign spaces were used for forecasting compound formation in A2MoO4-B2(MoO4)3 (5:1 ratio, where A-Li, Na, K, Rb, Cs; B-Al, In, Ga, Sc, Cr, Fe, Bi, La, Nd, Sm-Lu, Y) and A2MoO4-CMoO4 (1:2 ratio, where A-Li, Na, K, RB, Cs, Tl; C-Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pd, Mn, Co, Ni) systems: 1-electron distribution on energy shells of cations and their valency; 2-the type of incomplete electron shell, charge of cations, three first ionization potentials, standard heat capacity, ionic radius of cations; 3-standard formation enthalpy and standard entropy, oxide melting points and ionic radius of cations. It is shown that sign space, related with thermodynamic properties of oxides contains data, necessary for forecasting interaction in molybdate systems. This enables to improve reliability of forecasting
Additional details
Additional titles
- Original title (Russian)
- Влияние выбора системы признаков на прогноз образования соединений в системах А
Publishing Information
- Journal Title
- Dokl. Akad. Nauk SSSR
- Journal Volume
- 297
- Journal Issue
- 3
- Series
- Dokl. Akad. Nauk SSSR.
- Journal Page Range
- 646-649
- ISSN
- 0002-3264
- CODEN
- DANKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 19094907
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; ATOMIC RADII; CADMIUM COMPOUNDS; CATIONS; CHEMICAL REACTIONS; ELECTRONIC STRUCTURE; FORECASTING; IONIZATION POTENTIAL; MOLYBDATES; QUANTITY RATIO; REGRESSION ANALYSIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; VALENCE
- Descriptors DEC
- CHARGED PARTICLES; IONS; MATHEMATICS; MOLYBDENUM COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; STATISTICS