Published 1987 | Version v1
Journal article

Sign system choice influence on the substance formation forecast in A2MoO4-B2(MoO4)3 and A2MoO4-CMoO4 systems

  • 1. AN SSSR, Ulan-Ude. Inst. Estestvennykh Nauk

Description

Three sign spaces were used for forecasting compound formation in A2MoO4-B2(MoO4)3 (5:1 ratio, where A-Li, Na, K, Rb, Cs; B-Al, In, Ga, Sc, Cr, Fe, Bi, La, Nd, Sm-Lu, Y) and A2MoO4-CMoO4 (1:2 ratio, where A-Li, Na, K, RB, Cs, Tl; C-Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pd, Mn, Co, Ni) systems: 1-electron distribution on energy shells of cations and their valency; 2-the type of incomplete electron shell, charge of cations, three first ionization potentials, standard heat capacity, ionic radius of cations; 3-standard formation enthalpy and standard entropy, oxide melting points and ionic radius of cations. It is shown that sign space, related with thermodynamic properties of oxides contains data, necessary for forecasting interaction in molybdate systems. This enables to improve reliability of forecasting

Additional details

Additional titles

Original title (Russian)
Влияние выбора системы признаков на прогноз образования соединений в системах А

Publishing Information

Journal Title
Dokl. Akad. Nauk SSSR
Journal Volume
297
Journal Issue
3
Series
Dokl. Akad. Nauk SSSR.
Journal Page Range
646-649
ISSN
0002-3264
CODEN
DANKA