Published September 1978 | Version v1
Journal article

A modified derivation of the correlation factor in tracer diffusion via vacancy mechanism

  • 1. Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs.

Description

The average number of site exchanges made by a particular atom-vacancy pair has been calculated. It is found that the number of exchanges is equal to the number of visits to the origin of a random walker; for an infinite fcc lattice the number of exchanges is about 1.345, including the first exchange. This result seems invalidate the assumption of an infinite number of exchanges, which is usually made in the derivation of the correlation factor in diffusion via the vacancy mechanism. A modified derivation of the correlation factor, which takes into account the number of exchanges explicitly, is presented. (author)

Additional details

Publishing Information

Journal Title
J. Phys. Soc. Jpn.
Journal Volume
45
Journal Issue
3
Series
J. Phys. Soc. Jpn.
Journal Page Range
781-785