A novel hierarchical stiff carbon foam with graphene-like nanosheet surface as the desired adsorbent for malachite green removal from wastewater

A novel hierarchical stiff carbon foam (HSCF) was successfully prepared via a carbothermal reduction between the carbon foam with two-level pore structure and the Al₂O₃ from aluminum sulfate, and used as a bulk adsorbent for removing malachite green (MG) dye. The structures of the HSCF were characterized using SEM, XRD, FTIR, BET, and XPS, and the effects of adsorption condition on the MG removal were studied through batch adsorption experiments. Results show that large-sized and complex-shaped HSCF can be easily fabricated with a high compression strength of 1.58 MPa at a low bulk density (0.10 g cm⁻³). The HSCF possesses a fluffy graphene-like nanosheet surface with a mesoporous structure and meanwhile exhibits good hydrophilicity loaded with aluminum hydroxide. The experimental maximum adsorption capacity for MG reaches 425.2 mg g⁻¹ with a relatively high partition coefficient of 9.38 mg g⁻¹ μM⁻¹ at the optimal condition. The experimental data are in good agreement with Langmuir isotherm and pseudo-second-order kinetic model, and meanwhile, the adsorption of MG onto the HSCF is a spontaneous and endothermic process. Also, the HSCF still exhibits good adsorption ability and stability after seven regeneration cycles.