Published 1987
| Version v1
Book
ESR/ENDOR study of the guanine cation: Secondary product in 5' -dGMP
Description
Previous ESR studies by Voit and Huttermann of x-irradiated single crystals of 2' deoxyguanosine-5'-monophosphate have indicated the presence of a radical thought to be formed by deprotonation of the primary base cation at N1. In this study the authors report results of a detailed ESR and ENDOR experiment at 10 K which conflict with the results cited above. One of the radicals detected inhibited two α-proton type couplings. The data analysis shows that one coupling is due to the proton on the extra annular NH/sub 2/ group, while the other is due to the proton bonded to C8
Additional details
Publishing Information
- Publisher
- Radiation Research Society.
- Imprint Place
- Philadelphia, PA (USA)
- Imprint Title
- Thirty-fifth annual meeting of the Radiation Research Society (Abstracts)
- Journal Page Range
- p. 93.
Conference
- Title
- 35. annual meeting of the Radiation Research Society.
- Dates
- 22-26 Feb 1987.
- Place
- Atlanta, GA (USA).
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19044082
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference, Numerical Data
- Descriptors DEI
- CATIONS; CHEMICAL BONDS; CHEMICAL RADIATION EFFECTS; ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; GUANYLIC ACID; IRRADIATION; PROTONS; RADIATION CHEMISTRY; RADICALS
- Descriptors DEC
- BARYONS; CHARGED PARTICLES; CHEMISTRY; DATA; ELEMENTARY PARTICLES; FERMIONS; HADRONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; INFORMATION; IONS; MAGNETIC RESONANCE; NUCLEONS; NUCLEOTIDES; NUMERICAL DATA; ORGANIC COMPOUNDS; RADIATION EFFECTS; RESONANCE