Primary biogenic and anthropogenic sources of organic aerosols in Beijing, China: Insights from saccharides and n-alkanes

Highlights: • Biomass burning contributes significantly to PM_2.5 during the whole year, particularly in cold seasons. • n-Alkanes mainly originate from plant waxes in spring while from fossil fuel combustion in heating season. • Dust storms in spring account for high atmospheric levels of fine organic matter. Sugars and n-alkanes are important organic constituents of atmospheric fine particulate matter (PM_2.5). For better understanding their sources and seasonal variations in urban atmosphere, sugar compounds (anhydrosugars, sugars and sugar alcohols) and homologue n-alkanes (C₁₈–C₃₇) were studied in PM_2.5 samples collected from September 2013 to July 2014 in Beijing, China. In general, all measured compounds showed the lowest levels in summer. Higher concentrations of sugar compounds and n-alkanes were observed in winter, probably due to elevated combustion emissions (e.g., coal, biofuel and agricultural residue burning) and stable meteorological conditions during heating season. Levoglucosan was the major sugar species in all seasons particularly in autumn and winter, highlighting the significant contribution of biomass burning to fine organic aerosols throughout the whole year especially in cold seasons. Plant waxes contributed to n-alkanes the most in late spring (54.5%) and the least in winter (11.6%); while fossil fuel combustion had the largest contribution in winter (385 ng m⁻³). The weak odd-carbon predominance of n-alkanes in wintertime aerosols also suggests fossil fuel combustion as the important source of organic aerosols in the heating season. Soil resuspension, fossil fuel combustion and biomass burning, and secondary sources are the main sources of OC in PM_2.5 at Beijing. The seasonal variation in source contributions indicates that meteorological condition is a key factor in controlling PM_2.5 levels. Furthermore, dust storms in spring can strongly enhance the atmospheric level of fine organic matter in Beijing.