Published June 1983 | Version v1
Journal article

Chemical transport of vanadium silicides

  • 1. Akademie der Wissenschaften der DDR, Dresden. Zentralinstitut fuer Festkoerperphysik und Werkstofforschung

Description

Vanadium silicides VSi2, V5Si3, and V3Si have been prepared by chemical transport with Cl2 and SiCl4, respectively. X-ray diffraction patterns and measurements of superconductivity were used for the characterization of the individual phases formed in the transport tubes. Silicon-rich VSi2 and nonstoichiometric V3Si cannot be transported with Cl2 or SiCl4. The sequence, direction and rate of transport agree with the results of thermodynamic calculations. (author)

Additional details

Additional titles

Original title (German)
Zum chemischen Transport der Vanadiumsilicide

Publishing Information

Journal Title
Z. Anorg. Allg. Chem.
Journal Volume
501
Series
Z. Anorg. Allg. Chem.
Journal Page Range
27-39
ISSN
0044-2313