Published 1973 | Version v1
Journal article Metadata-only

Pentacarbonyl(organometallic telluride)chromium, molybdenum and tungsten complexes

Creators

  • 1. Technische Univ. Berlin (F.R. Germany). Anorganische und Analytische Chemie

Description

Trimethylgermanium, -tin, and -lead chlorides react with sodium telluride to form bis(trimethylgermyl)telluride (1), bis(trimethylstannyl)telluride (2), and bis(trimethylplumbyl)telluride (3). These organometallic tellurides form corresponding pentacarbonyl(organometallic telluride)chromium(0), -molybdenum(0), and -tungsten(0) complexes 4 – 12 upon the elimination of a CO ligand with hexacarbonylchromium, -molybdenum, and -tungsten. The IR, Raman, and 1H-NMR spectra are discussed.

Abstract (German)

Trimethylgermanium‐, ‐zinn‐ und ‐bleichlorid reagieren mit Natriumtellurid unter Bildung von Bis(trimethylgermyl)‐ ( 1 ), Bis(trimethylstannyl)‐ ( 2 ) und Bis(trimethylplumbyl)tellurid ( 3 ). Diese Organometalltelluride bilden mit Hexacarbonylchrom, ‐molybdän und ‐wolfram unter Abspaltung eines CO‐Liganden entsprechende Pentacarbonyl(organometalltellurid)‐chrom(0)‐, ‐molybdän(0)‐ bzw. ‐wolfram(0)‐Komplexe 4 – 12 . Die IR‐, Raman‐ und 1 H‐NMR‐Spektren werden diskutiert.

Additional details

Additional titles

Original title (German)
Pentacarbonyl(organometalltellurid)chrom-, -molybdaen- und -wolfram-Komplexe

Identifiers

DOI
10.1002/cber.19731060633;

Publishing Information

Journal Title
Chemische Berichte
Journal Volume
106
Journal Issue
6
Series
Chem. Ber.
Journal Page Range
2049-2057
ISSN
0009-2940

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
4084564
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBONYLS; CHROMIUM COMPLEXES; CHROMIUM COMPOUNDS; GERMANIUM CHLORIDES; INFRARED SPECTRA; LEAD CHLORIDES; LIGANDS; MOLYBDENUM COMPLEXES; MOLYBDENUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLIC COMPOUNDS; RAMAN EFFECT; TELLURIDES; TELLURIUM COMPLEXES; TELLURIUM COMPOUNDS; TIN CHLORIDES; TUNGSTEN COMPLEXES; TUNGSTEN COMPOUNDS
Descriptors DEC
CHALCOGENIDES; CHLORIDES; COMPLEXES; GERMANIUM COMPOUNDS; HALIDES; LEAD COMPOUNDS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RESONANCE; SPECTRA; TIN COMPOUNDS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
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