Laser-induced conical intersections in molecular optical lattices
- 1. Schulich Faculty of Chemistry and Minerva Center of Nonlinear Physics in Complex Systems, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
- 2. Theoretische Chemie, Physikalisch-Chemisches Institut, Universitaet Heidelberg, D-69120, Heidelberg (Germany)
Description
Conical intersections of potential energy surfaces widely appear in molecules which consist of more than two atoms. No conical intersections exist in the case of free diatomic molecules. We show here that diatomic molecules interacting with standing laser waves produce periodic arrays of conical intersections. At these laser-induced intersections the non-adiabatic effects are infinitely strong. The translational and rovibrational molecular motions become strongly coupled to each other and energy exchange between the various degrees of freedom influences the dynamics of the system. As an illustrative example, an effect of the laser-induced conical intersections on trapping of ultracold diatomic molecules by light is discussed. (fast track communication)
Availability note (English)
Available from http://dx.doi.org/10.1088/0953-4075/41/22/221001Additional details
Identifiers
- DOI
- 10.1088/0953-4075/41/22/221001;
- PII
- S0953-4075(08)91177-9;
Publishing Information
- Journal Title
- Journal of Physics. B, Atomic, Molecular and Optical Physics
- Journal Volume
- 41
- Journal Issue
- 22
- Journal Page Range
- [5 p.]
- ISSN
- 0953-4075
- CODEN
- JPAPEH
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41008244
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOMS; DEGREES OF FREEDOM; ENERGY TRANSFER; INTERFERENCE; LASER RADIATION; MOLECULES; PERIODICITY; POTENTIAL ENERGY; STARK EFFECT; SURFACES; TRAPPING
- Descriptors DEC
- ELECTROMAGNETIC RADIATION; ENERGY; RADIATIONS; VARIATIONS