Published November 28, 2008 | Version v1
Journal article

Laser-induced conical intersections in molecular optical lattices

  • 1. Schulich Faculty of Chemistry and Minerva Center of Nonlinear Physics in Complex Systems, Technion-Israel Institute of Technology, Haifa 32000 (Israel)
  • 2. Theoretische Chemie, Physikalisch-Chemisches Institut, Universitaet Heidelberg, D-69120, Heidelberg (Germany)

Description

Conical intersections of potential energy surfaces widely appear in molecules which consist of more than two atoms. No conical intersections exist in the case of free diatomic molecules. We show here that diatomic molecules interacting with standing laser waves produce periodic arrays of conical intersections. At these laser-induced intersections the non-adiabatic effects are infinitely strong. The translational and rovibrational molecular motions become strongly coupled to each other and energy exchange between the various degrees of freedom influences the dynamics of the system. As an illustrative example, an effect of the laser-induced conical intersections on trapping of ultracold diatomic molecules by light is discussed. (fast track communication)

Availability note (English)

Available from http://dx.doi.org/10.1088/0953-4075/41/22/221001

Additional details

Identifiers

DOI
10.1088/0953-4075/41/22/221001;
PII
S0953-4075(08)91177-9;

Publishing Information

Journal Title
Journal of Physics. B, Atomic, Molecular and Optical Physics
Journal Volume
41
Journal Issue
22
Journal Page Range
[5 p.]
ISSN
0953-4075
CODEN
JPAPEH

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41008244
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOMS; DEGREES OF FREEDOM; ENERGY TRANSFER; INTERFERENCE; LASER RADIATION; MOLECULES; PERIODICITY; POTENTIAL ENERGY; STARK EFFECT; SURFACES; TRAPPING
Descriptors DEC
ELECTROMAGNETIC RADIATION; ENERGY; RADIATIONS; VARIATIONS