Published March 1993 | Version v1
Journal article

About synthesis of transition metals n,π-binuclear complexes with the participation of the Os3-cluster. Structures of three new arenetetracobaltnonacarbonyls

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Ehlementoorganicheskikh Soedinenij

Description

Interaction of osmium complex MesCH2CNOs3(CO)11 (Mes-mesityl) with Py3Mo(CO)3 in anhydrous ether solution in the presence of BF3 · OEt2 resulted in (CO)3MoMesCH2CNOs3(CO)11 complex formation. The yield of the complex was 7 %. The complex was characterized by IR-spectra and chemical analysis data

Additional details

Additional titles

Original title (Russian)
О синтезе н,Ï€-биядерных комплексов переходных металлов с участием Ос

Publishing Information

Journal Title
Metalloorganicheskaya Khimiya
Journal Volume
6
Journal Issue
2
Journal Page Range
p. 218-230.
ISSN
0235-0114
CODEN
MEKHEX

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
24074129
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; MOLYBDENUM COMPLEXES; OSMIUM COMPLEXES; SOLID CLUSTERS
Descriptors DEC
COMPLEXES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS