Different effects of grain boundary scattering on charge and heat transport in polycrystalline platinum and gold nanofilms

The in-plane electrical and thermal conductivities of several polycrystalline platinum and gold nanofilms with different thicknesses are measured in a temperature range between the boiling point of liquid nitrogen (77 K) and room temperature by using the direct current heating method. The result shows that both the electrical and thermal conductivities of the nanofilms reduce greatly compared with their corresponding bulk values. However, the electrical conductivity drop is considerably greater than the thermal conductivity drop, which indicates that the influence of the internal grain boundary on heat transport is different from that of charge transport, hence leading to the violation of the Wiedemann–Franz law. We build an electron relaxation model based on Matthiessen's rule to analyse the thermal conductivity and employ the Mayadas and Shatzkes theory to analyse the electrical conductivity. Moreover, a modified Wiedemann–Franz law is provided in this paper, the obtained results from which are in good agreement with the experimental data