Inferring nonequilibrium thermodynamics from tilted equilibrium using information-geometric Legendre transform
Creators
- 1. Department of Physics, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
Description
Nonstationary thermodynamic quantities depend on the full details of nonstationary probability distributions, making them difficult to measure directly in experiments and numerics. We propose a method to infer thermodynamic quantities in relaxation processes by measuring only a few observables, using additional information obtained from measurements in tilted equilibrium, i.e., equilibrium with external fields applied. Our method is applicable to arbitrary classical stochastic systems, possibly underdamped, that relax to equilibrium. The method allows us to compute the exact value of the minimum entropy production (EP) compatible with the nonstationary observations, giving a tight lower bound on the true EP. Under a certain additional condition, it also allows the inference of the EP rate, thermodynamic forces, and a constraint on relaxation paths. Our method uses a Legendre transform of EP at the level of probability distributions, which we develop based on a similar Legendre transform in information geometry.
Files
10.1103_PhysRevResearch.6.013315.pdf
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Additional details
Identifiers
- DOI
- 10.1103/PhysRevResearch.6.013315;
- arXiv
- arXiv:2112.11008;
- Crossref Funder ID
- 10.13039/501100001691; 10.13039/501100001695;
Publishing Information
- Journal Title
- Physical Review Research
- Journal Volume
- 6
- Journal Issue
- 1
- Journal Page Range
- 15 pgs.
- ISSN
- 2643-1564
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S97: MATHEMATICAL METHODS AND COMPUTING;
- Descriptors DEI
- DISTRIBUTION; DYNAMICAL SYSTEMS; ENTROPY; EQUILIBRIUM; HEAT ENGINES; INFORMATION; LIMITING VALUES; MATHEMATICAL EVOLUTION; PROBABILITY; RELAXATION; RELAXATION TIME; STATISTICAL MECHANICS; STOCHASTIC PROCESSES; THERMAL EQUILIBRIUM; THERMODYNAMICS
- Descriptors DEC
- ENGINES; EQUILIBRIUM; EVOLUTION; MECHANICS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES
Optional Information
- Contract/Grant/Project number
- 23KJ0732; 19H05796; 21H01560; 22H01141; 23H00467; JPMJPR18M2; JPMJER2302
- Notes
- Contact Email: naruo.ohga@ubi.s.u-tokyo.ac.jp; Record automatically processed
- Funding organization
- Japan Society for the Promotion of Science; Japan Science and Technology Corporation