Published March 22, 2024 | Version v1
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Inferring nonequilibrium thermodynamics from tilted equilibrium using information-geometric Legendre transform

  • 1. Department of Physics, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Description

Nonstationary thermodynamic quantities depend on the full details of nonstationary probability distributions, making them difficult to measure directly in experiments and numerics. We propose a method to infer thermodynamic quantities in relaxation processes by measuring only a few observables, using additional information obtained from measurements in tilted equilibrium, i.e., equilibrium with external fields applied. Our method is applicable to arbitrary classical stochastic systems, possibly underdamped, that relax to equilibrium. The method allows us to compute the exact value of the minimum entropy production (EP) compatible with the nonstationary observations, giving a tight lower bound on the true EP. Under a certain additional condition, it also allows the inference of the EP rate, thermodynamic forces, and a constraint on relaxation paths. Our method uses a Legendre transform of EP at the level of probability distributions, which we develop based on a similar Legendre transform in information geometry.

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10.1103_PhysRevResearch.6.013315.pdf

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Additional details

Identifiers

DOI
10.1103/PhysRevResearch.6.013315;
arXiv
arXiv:2112.11008;
Crossref Funder ID
10.13039/501100001691; 10.13039/501100001695;

Publishing Information

Journal Title
Physical Review Research
Journal Volume
6
Journal Issue
1
Journal Page Range
15 pgs.
ISSN
2643-1564

Optional Information

Contract/Grant/Project number
23KJ0732; 19H05796; 21H01560; 22H01141; 23H00467; JPMJPR18M2; JPMJER2302
Notes
Contact Email: naruo.ohga@ubi.s.u-tokyo.ac.jp; Record automatically processed
Funding organization
Japan Society for the Promotion of Science; Japan Science and Technology Corporation