Published February 2007 | Version v1
Journal article Metadata-only

Thermochemical characteristics of the LnCl4- and Ln2Cl7- negative ions

Creators

  • 1. Ivanovskij Gosudarstvennyj Khimiko-Tekhnologicheskij Univ., Ivanovo (Russian Federation)

Description

The literature data on the thermochemical characteristics of negative LnCl4- and Ln2Cl7- ions (from lanthanum to lutetium inclusive) in the gas phase are systematized. The enthalpies of ion-molecular and ion-ion reactions with the participation of these ions were calculated and used to determine the enthalpies of formation of the ions for the whole lanthanide series

Abstract (Russian)

Проведена систематизация литературных данных по термохимии газообразных отрицательных ионов лантанидов LnCl4- и Ln2Cl7- (от лантана до лютеция включительно). Рассчитаны энтальпии ионно-молекулярных и ионно-ионных реакций с участием указанных ионов и на их основе определены энтальпии образования ионов для всей лантанидной серии

Additional details

Additional titles

Original title (Russian)
Термохимия отрицательных ионов LnCl

Publishing Information

Journal Title
Zhurnal Fizicheskoj Khimii
Journal Volume
81
Journal Issue
2
Journal Page Range
p. 199-210
ISSN
0044-4537
CODEN
ZFKHA9

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
38062779
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ANIONS; CHEMICAL COMPOSITION; CHEMICAL REACTIONS; CHLORIDES; EQUILIBRIUM; EVALUATED DATA; GASES; MASS SPECTROSCOPY; RARE EARTH COMPLEXES; REACTION HEAT; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0400-1000 K; TEMPERATURE RANGE 1000-4000 K
Descriptors DEC
CHARGED PARTICLES; CHLORINE COMPOUNDS; COMPLEXES; DATA; ENTHALPY; FLUIDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; IONS; NUMERICAL DATA; PHYSICAL PROPERTIES; SPECTROSCOPY; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES

Optional Information

Notes
26 refs., 4 figs., 10 tabs.