Published April 2013 | Version v1
Journal article Metadata-only

An azafluorenone alkaloid and a megastigmane from Unonopsis lindmanii (Annonaceae)

Creators

  • 1. Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Quimica
  • 2. Universidade Federal de Sao Joao Del Rei, Divinpolis, MG (Brazil). Departamento de Farmacia
  • 3. Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas
  • 4. Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Ciencias Biomedicas
  • 5. Universidade Federal de Mato Grosso do Sul (UFMS), Campo Grande, MS (Brazil). Departamento de Quimica

Description

The azafluorenone alkaloid 5,8-dimethoxy-7-hydroxy-1-methyl-4-azafluoren-9-one and the megastigman (–)-(5R*, 6S*)-megastigman-3-one-10,7-olide were isolated from aerial parts of Unonopsis lindmanii (Annonaceae), along with the known compounds (3S*,5S*,8R*)-3,5-dihydroxymegastigma-6,7-dien-9-one (grasshopper ketone), N-trans-feruloyltyramine, (–)-anonaine, (–)-asimilobine, liriodenine and (–)-syringaresinol. This is the first description of the presence of megastigmanes in Annonaceae. The structures of the compounds were elucidated based on spectroscopic data. (author)

Availability note (English)

Available from http://www.scielo.br/pdf/jbchs/v24n4/v24n4a02.pdf

Additional details

Identifiers

URL
http://www.scielo.br/pdf/jbchs/v24n4/v24n4a02.pdf;

Publishing Information

Journal Title
Journal of the Brazilian Chemical Society
Journal Volume
24
Journal Issue
4
Journal Page Range
p. 529-533
ISSN
0103-5053
CODEN
JOCSET

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
44093163
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETATES; ALKALOIDS; CARBON 13; CARBONYLS; CHEMICAL SHIFT; CHLOROFORM; GLUTAMIC ACID; HEXANE; HYDROGEN 1; INFRARED SPECTRA; LIQUID COLUMN CHROMATOGRAPHY; NMR SPECTRA; PH VALUE; SILICA GEL; SITOSTEROL; THIN-LAYER CHROMATOGRAPHY; TYRAMINE
Descriptors DEC
ADSORBENTS; ALKANES; AMINES; AMINO ACIDS; AROMATICS; AUTONOMIC NERVOUS SYSTEM AGENTS; CARBON ISOTOPES; CARBOXYLIC ACID SALTS; CARBOXYLIC ACIDS; CHLORINATED ALIPHATIC HYDROCARBONS; CHROMATOGRAPHY; DRUGS; EVEN-ODD NUCLEI; HALOGENATED ALIPHATIC HYDROCARBONS; HYDROCARBONS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC ACIDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHENOLS; SEPARATION PROCESSES; SPECTRA; STABLE ISOTOPES; STEROIDS; STEROLS; SYMPATHOMIMETICS