Published 2019 | Version v1
Journal article Metadata-only

The effect of ceria and zirconia nanoparticles on the corrosion behaviour of cataphoretic epoxy coatings on AA6060 alloy

Creators

Description

In this work an attempt was made to produce epoxy coating doped with ceria (CeO2) and/or zirconia (ZrO2) nanoparticles, in single step electrophoretric deposition process. Deposition was carried out on AA6060 cataforetically from epoxy resin suspension containing synthesized stable aqueous colloidal dispersions (sols) of CeO2 and ZrO2. The influence of ceria and zirconia nanoparticles on the physicochemical characteristics of epoxy coatings was evaluated by energy dispersive X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis and adhesion measurements, while their corrosion stability during immersion in 0.5 M NaCl solution was monitored by electrochemical impedance spectroscopy. All ceria and/or zirconia containing coatings showed better corrosion stability and adhesion than pure epoxy coating, while between doped epoxy coatings one with CeO2/ZrO2 exhhibited the greatest values of charge-transfer resistance due to synergetic effect of both types of added nanoparticles. © 2019 Elsevier B.V.

Availability note (English)

Available from http://vinar.vin.bg.ac.rs/handle/123456789/8422

Additional details

Identifiers

URL
http://vinar.vin.bg.ac.rs/handle/123456789/8422;
DOI
10.1016/j.porgcoat.2019.105219;

Publishing Information

Journal Title
Progress in Organic Coatings (Print)
Journal Volume
136
Journal Page Range
p. 105219
ISSN
0300-9440

INIS

Country of Publication
Switzerland
Country of Input or Organization
Serbia
INIS RN
51109810
Subject category
S77: NANOSCIENCE AND NANOTECHNOLOGY;
Descriptors DEI
ALLOYS; CERIUM OXIDES; COATINGS; CORROSION; CRYSTAL LATTICES; DEPOSITION; DOPED MATERIALS; ELECTROCHEMISTRY; EPOXIDES; FIELD EMISSION; FOURIER TRANSFORM SPECTROMETERS; NANOPARTICLES; SCANNING ELECTRON MICROSCOPY; SODIUM CHLORIDES; SOLUTIONS; SUSPENSIONS; THERMAL GRAVIMETRIC ANALYSIS; X-RAY PHOTOELECTRON SPECTROSCOPY; ZIRCONIUM OXIDES
Descriptors DEC
ALKALI METAL COMPOUNDS; CERIUM COMPOUNDS; CHALCOGENIDES; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; CHEMISTRY; CHLORIDES; CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; DISPERSIONS; ELECTRON MICROSCOPY; ELECTRON SPECTROSCOPY; EMISSION; GRAVIMETRIC ANALYSIS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; MATERIALS; MEASURING INSTRUMENTS; MICROSCOPY; MIXTURES; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PARTICLES; PHOTOELECTRON SPECTROSCOPY; QUANTITATIVE CHEMICAL ANALYSIS; RARE EARTH COMPOUNDS; SODIUM COMPOUNDS; SODIUM HALIDES; SPECTROMETERS; SPECTROSCOPY; THERMAL ANALYSIS; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS

Optional Information

Notes
OAI: vinar.vin.bg.ac.rs:123456789/8422