Published May 2009
| Version v1
Journal article
Comment on 'Ground state of octahedral platinum hexafluoride'
Creators
- 1. Institute of Inorganic Chemistry of Siberian Department, RAS, Av. Lavrent'eva 3, Novosibirsk 630090 (Russian Federation)
Description
It is shown that the principal results of a recent work by Alvarez-Thon et al. [Phys. Rev. A 77, 034502 (2008)] are in conflict with earlier work of the present authors [JETP Lett. 73, 35 (2001)] and also with a well known result concerning magnetic properties, NMR, and Jahn-Teller effect in the systems possessing even number of d electrons. This can be attributed to the fact that Alvarez-Thon et al. did not account for the influence of 19F and 195Pt nuclear magnetic moments and vibronic interactions on the wave function of PtF6 molecules.
Additional details
Identifiers
Publishing Information
- Journal Title
- Physical Review. A
- Journal Volume
- 79
- Journal Issue
- 5
- Journal Page Range
- p. 056501-056501.2
- ISSN
- 1050-2947
- CODEN
- PLRAAN
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41056461
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CHEMICAL SHIFT; DIRAC EQUATION; ELECTRONS; FLUORINE 19; GROUND STATES; HARTREE-FOCK METHOD; JAHN-TELLER EFFECT; MAGNETIC PROPERTIES; MOLECULES; NUCLEAR MAGNETIC MOMENTS; NUCLEAR MAGNETIC RESONANCE; PLATINUM; PLATINUM 195; PLATINUM COMPOUNDS; VIBRATIONAL STATES; WAVE FUNCTIONS
- Descriptors DEC
- APPROXIMATIONS; CALCULATION METHODS; DAYS LIVING RADIOISOTOPES; DIFFERENTIAL EQUATIONS; ELEMENTARY PARTICLES; ELEMENTS; ENERGY LEVELS; EQUATIONS; EVEN-ODD NUCLEI; EXCITED STATES; FERMIONS; FIELD EQUATIONS; FLUORINE ISOTOPES; FUNCTIONS; HEAVY NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; LEPTONS; LIGHT NUCLEI; MAGNETIC MOMENTS; MAGNETIC RESONANCE; METALS; NUCLEAR PROPERTIES; NUCLEI; ODD-EVEN NUCLEI; PARTIAL DIFFERENTIAL EQUATIONS; PHYSICAL PROPERTIES; PLATINUM ISOTOPES; PLATINUM METALS; RADIOISOTOPES; RESONANCE; STABLE ISOTOPES; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; WAVE EQUATIONS
Optional Information
- Notes
- (c) 2009 The American Physical Society