Adsorption of Pb(II) and Cr(III) from aqueous solution on Celtek clay
- 1. Department of Chemistry, Gaziosmanpasa University, 60250 Tokat (Turkey)
- 2. Department of Chemistry, Erciyes University, 38039 Kayseri (Turkey)
Description
This paper presents the adsorption of Pb(II) and Cr(III) from aqueous solution on Celtek clay. Batch experiments were carried out as a function of the adsorbent dosage, solution pH, shaking time, and temperature. The equilibrium data of fitted well with the linear Langmuir and Freundlich models. Dubinin-Radushkevick (D-R) isotherm model was applied to describe the nature of the adsorption of the metals, and found that it occurred physically. Thermodynamic parameters, the change in Gibbs free energy change (ΔGo), enthalpy (ΔHo) and entropy (ΔSo) were also calculated. These parameters indicated that the adsorption of Pb(II) and Cr(III) on Celtek clay was feasible, spontaneous and exothermic process in nature. Based on the results, it was concluded that Celtek clay had a significant potential for removing Pb(II) and Cr(III) from wastewater using adsorption method
Additional details
Identifiers
- DOI
- 10.1016/j.jhazmat.2006.09.080;
- PII
- S0304-3894(06)01159-9;
Publishing Information
- Journal Title
- Journal of Hazardous Materials
- Journal Volume
- 144
- Journal Issue
- 1-2
- Journal Page Range
- p. 41-46
- ISSN
- 0304-3894
- CODEN
- JHMAD9
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39018197
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S54: ENVIRONMENTAL SCIENCES;
- Descriptors DEI
- ADSORBENTS; ADSORPTION; ADSORPTION ISOTHERMS; AQUEOUS SOLUTIONS; CHROMIUM; CLAYS; ENTHALPY; ENTROPY; FREE ENTHALPY; LEAD; PH VALUE; WASTE WATER; WATER POLLUTION; WATER POLLUTION CONTROL
- Descriptors DEC
- CONTROL; DISPERSIONS; ELEMENTS; ENERGY; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; ISOTHERMS; LIQUID WASTES; METALS; MINERALS; MIXTURES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POLLUTION; POLLUTION CONTROL; SILICATE MINERALS; SOLUTIONS; SORPTION; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENTS; WASTES; WATER
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.