Uniform WKB theory of multichannel predissociation and inelastic scattering
Description
In this paper the uniform WKB theory is applied to predissociations of N curve crossing systems as an extension of the study we made in a previous paper. We have obtained transition amplitudes (S-matrix elements) explicitly for three-state and N-state problems in terms of the transition factors and phase integrals used previously in our study of two-state problems. The expressions obtained in the local pairwise coupling approximation are extremely simple, physically transparent, and easy to compute. Within the framework of this model we have obtained the resonance characteristics for predissociative N-curve crossing problems. The level width formula is given in terms of the transition factors chi/sub i/ and is new. The transition amplitudes for the corresponding inelastic scattering problems were also derived
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 70
- Journal Issue
- 11
- Series
- J. Chem. Phys.
- Journal Page Range
- 4986-4994
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10486037
- Subject category
- S72: PHYSICS OF ELEMENTARY PARTICLES AND FIELDS;
- Descriptors DEI
- INELASTIC SCATTERING; PREDISSOCIATION; S MATRIX; TRANSITION AMPLITUDES; WKB APPROXIMATION
- Descriptors DEC
- AMPLITUDES; DISSOCIATION; MATRICES; SCATTERING