Published June 1, 1979 | Version v1
Journal article

Uniform WKB theory of multichannel predissociation and inelastic scattering

  • 1. Department of Chemistry, McGill University, Montreal, Canada

Description

In this paper the uniform WKB theory is applied to predissociations of N curve crossing systems as an extension of the study we made in a previous paper. We have obtained transition amplitudes (S-matrix elements) explicitly for three-state and N-state problems in terms of the transition factors and phase integrals used previously in our study of two-state problems. The expressions obtained in the local pairwise coupling approximation are extremely simple, physically transparent, and easy to compute. Within the framework of this model we have obtained the resonance characteristics for predissociative N-curve crossing problems. The level width formula is given in terms of the transition factors chi/sub i/ and is new. The transition amplitudes for the corresponding inelastic scattering problems were also derived

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
70
Journal Issue
11
Series
J. Chem. Phys.
Journal Page Range
4986-4994
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
10486037
Subject category
S72: PHYSICS OF ELEMENTARY PARTICLES AND FIELDS;
Descriptors DEI
INELASTIC SCATTERING; PREDISSOCIATION; S MATRIX; TRANSITION AMPLITUDES; WKB APPROXIMATION
Descriptors DEC
AMPLITUDES; DISSOCIATION; MATRICES; SCATTERING