Published August 1993 | Version v1
Journal article Metadata-only

The role of charge-transfer complex in radiolysis of compatible mixtures of polyvinylmethyl ester and aromatic vinyl monomers

Creators

Description

It was found with ESR, optical absorption and liminescence methods that substantial negative deviation from additivity of radiochemical yield of paramagnetic centers is observed at low-temperature radiolysis of single-phase mixtures of PS (or polyvinyltoluene) and polyvinylmethyl ester due to electron capture by intercomponent electron-transfer complex. In phase-separated mixtures of the same components the effect is not observed

Additional details

Additional titles

Original title (Russian)
Роль комплекса с переносом заряда при радиолизе совместимых смесей поливинилметилового эфира с ароматическими виниловыми полимерами

Publishing Information

Journal Title
Vysokomolekulyarnye Soedineniya, Seriya A
Journal Volume
35
Journal Issue
8
Journal Page Range
p. 1272-1277.
ISSN
0507-5475
CODEN
VYSAAF

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
25043076
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHARGE TRANSPORT; DOSE RATES; ELECTRON SPIN RESONANCE; G VALUE; GAMMA RADIATION; LUMINESCENCE; POLYVINYLS; RADIOLYSIS
Descriptors DEC
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; EMISSION; IONIZING RADIATIONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC POLYMERS; PHOTON EMISSION; POLYMERS; RADIATION EFFECTS; RADIATIONS; RESONANCE