Published 1983
| Version v1
Journal article
Charge-transfer complexes between p-toluidine and iodine in solution
- 1. Consiglio Nazionale delle Ricerche (C.N.R.), Bologna (Italy). Istituto di Fotochimica e Radiazioni d'Alta Energia
- 2. Universita degli Studi di Bologna, Bologna (Italy). Istituto Chimico 'G. Ciamician'
Description
The charge-transfer interaction between an aromatic amine (p-toluidine) and a halogen (iodine) is investigated in different solvents. The effects of the solvent dielectric constant, of the ionic strength and of the light absorbed on the transformation of the intermediate 'outer' complex into a polar 'inner' structure are studied. An overall reaction mechanism is suggested. (Author)
Additional details
Additional titles
- Subtitle (English)
- A spectrophotometric and voltammetric study
Publishing Information
- Journal Title
- Monatsh. Chem.
- Journal Volume
- 114
- Journal Issue
- 6/7
- Series
- Monatsh. Chem.
- Journal Page Range
- 675-685
- ISSN
- 0026-9247
INIS
- Country of Publication
- Austria
- Country of Input or Organization
- Austria
- INIS RN
- 14791473
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- IODINE COMPLEXES; SPECTROPHOTOMETRY; TOLUIDINES; VOLTAMETRY
- Descriptors DEC
- AMINES; COMPLEXES; ORGANIC COMPOUNDS