Published September 15, 1972 | Version v1
Journal article

Probabilistic interpretation of cluster function series development of many-electron wave functions

Description

A probabilistic treatment of the polyfermionic systems is made. The idea of the particles localizability on bounded sets in the X-configuration space of the system is used. The decomposition of this space into a union of bounded sets permits a natural decomposition of the wavefunction into a cluster function series. Our purposes are (a) a physical interpretation of this type of expansion and (b) the establishment of a definition for the correlation phenomenon independently of a Hartree-Fock or other particular model.

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
57
Journal Issue
6
Series
J. Chem. Phys.
Journal Page Range
2581-2585
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
4049055
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOMS; CLUSTER EXPANSION; ELECTRON CORRELATION; ELECTRONIC STRUCTURE; SERIES EXPANSION; WAVE FUNCTIONS
Descriptors DEC
CORRELATIONS; FUNCTIONS

Optional Information

Notes
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