Aliovalent doping of niobium and tantalum pentoxide as potential alternative support material for fuel cell catalysts

As the usually used Carbon Blacks (CB) as support materials in fuel cell catalysts are thermodynamically unstable, alternative supports with high chemical stability and electrical conductivity are to be found. After the investigation of Nb and Ta-doped SnO${}_2$ in an earlier publication, which revealed interesting conductivity properties, we expanded our portfolio of mutual doping of elements of stable oxides into the oxides of the others by reporting here on the Sn, Hf and W-doping as guests into the base oxides Nb${}_2$O${}_5$ and Ta${}_2$O${}_5$. The changes in unit cell parameters as indicators for the doping success were investigated in the doping range of x=0-10 mol % guest fraction. From a complete solubility of the guest ions in case of Hf and W-doping in the base oxides to a limited solubility in case of Sn-doping, a whole spectrum of different results was obtained. Additional insight came from UV/vis spectroscopic investigations in diffuse reflectance as well as electrical conductivity measurements. (© 2024 The Author(s). Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH)