Published January 2013 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine

Creators

  • 1. Inst. of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau (Moldova, Republic of)
  • 2. Inst. of Applied Physics, Academy of Sciences of Moldova, 5, Academiei str., MD-2028, Chisinau (Moldova, Republic of)

Description

The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyoxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]x2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding. (authors)

Availability note (English)

Available online at http://www.cjm.asm.md/

Additional details

Identifiers

URL
http://www.cjm.asm.md/;

Publishing Information

Journal Title
Chemistry Journal of Moldova
Journal Volume
8
Journal Issue
1
Journal Page Range
p. 78-82
ISSN
1857-1727

INIS

Country of Publication
Moldova, Republic of
Country of Input or Organization
Moldova, Republic of
INIS RN
44102254
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL STRUCTURE; IRON COMPOUNDS; SYNTHESIS; TRIAZINES; X-RAY DIFFRACTION
Descriptors DEC
AZINES; COHERENT SCATTERING; DIFFRACTION; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
29 refs., 2 tabs., 2 figs.