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Published January 2020 | Version v1
Journal article

Crystal Structure of the New Ordered Phases Based on Y2Ba3Fe3Co2O13 + δ

  • 1. Ural Federal University name after the First President of Russia B.N. Yeltsin (Russian Federation)

Description

New phases with an ordered structure of the composition Y2Ba3Fe5– yCoyO13 + δ (1.7 ≤ y ≤ 2.1) were obtained via the glycerol-nitrate technique. The regions of existence of two types of structures were determined by transmission electron microscopy: for 1.7 ≤ y ≤ 1.8, the structure described as ap × ap × 3ap, and for 1.9 ≤ y ≤ 2.1, it is ap × ap × 5ap, where ap is the parameter of the ideal cubic perovskite. The unit cell parameters for all single-phase samples were refined by the Le Bail method. The phase composition of oxides outside the homogeneity ranges is determined.

Additional details

Identifiers

Publishing Information

Journal Title
Inorganic Materials
Journal Volume
56
Journal Issue
1
Journal Page Range
p. 72-76
ISSN
0020-1685
CODEN
INOMAF

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Copyright
Copyright (c) 2020 © Pleiades Publishing, Ltd. 2020