Published February 17, 2014 | Version v1
Journal article

Macroscopic dynamics near the isotropic micellar to lamellar phase transition

Description

Highlights: • The hydrodynamic equations near the I-LD transition are investigated. • The macroscopic dynamic equations are presented. • The experimental consequences of the theory are discussed. - Abstract: We present the hydrodynamic equations for the lamellar phase in lyotropic liquid crystals. The hydrodynamic equations are investigated to the vicinity of the isotropic micellar to lamellar phase transition. To derive the hydrodynamic equations we make use of symmetry arguments and irreversible thermodynamics. Besides the usual order parameters to describe the lamellar phase we also keep the concentration of the surfactant molecules which are aggregated in micelles as a variable in order to describe the correct macroscopic behavior of the lamellar phase. The macroscopic dynamic equations are presented on both sides of the transition. We discuss possible experiment were our theory can be tested

Availability note (English)

Available from http://dx.doi.org/10.1016/j.chemphys.2013.12.012

Additional details

Identifiers

DOI
10.1016/j.chemphys.2013.12.012;
PII
S0301-0104(13)00462-X;

Publishing Information

Journal Title
Chemical Physics
Journal Volume
430
Journal Page Range
p. 56-61
ISSN
0301-0104
CODEN
CMPHC2

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
46124910
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CONCENTRATION RATIO; DIFFERENTIAL EQUATIONS; HYDRODYNAMICS; LIQUID CRYSTALS; MOLECULES; ORDER PARAMETERS; PHASE TRANSFORMATIONS; SURFACTANTS; SYMMETRY; THERMODYNAMICS
Descriptors DEC
CRYSTALS; DIMENSIONLESS NUMBERS; EQUATIONS; FLUID MECHANICS; FLUIDS; LIQUIDS; MECHANICS

Optional Information

Copyright
Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.