Macroscopic dynamics near the isotropic micellar to lamellar phase transition
Creators
Description
Highlights: • The hydrodynamic equations near the I-LD transition are investigated. • The macroscopic dynamic equations are presented. • The experimental consequences of the theory are discussed. - Abstract: We present the hydrodynamic equations for the lamellar phase in lyotropic liquid crystals. The hydrodynamic equations are investigated to the vicinity of the isotropic micellar to lamellar phase transition. To derive the hydrodynamic equations we make use of symmetry arguments and irreversible thermodynamics. Besides the usual order parameters to describe the lamellar phase we also keep the concentration of the surfactant molecules which are aggregated in micelles as a variable in order to describe the correct macroscopic behavior of the lamellar phase. The macroscopic dynamic equations are presented on both sides of the transition. We discuss possible experiment were our theory can be tested
Availability note (English)
Available from http://dx.doi.org/10.1016/j.chemphys.2013.12.012Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2013.12.012;
- PII
- S0301-0104(13)00462-X;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 430
- Journal Page Range
- p. 56-61
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 46124910
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- CONCENTRATION RATIO; DIFFERENTIAL EQUATIONS; HYDRODYNAMICS; LIQUID CRYSTALS; MOLECULES; ORDER PARAMETERS; PHASE TRANSFORMATIONS; SURFACTANTS; SYMMETRY; THERMODYNAMICS
- Descriptors DEC
- CRYSTALS; DIMENSIONLESS NUMBERS; EQUATIONS; FLUID MECHANICS; FLUIDS; LIQUIDS; MECHANICS
Optional Information
- Copyright
- Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.