Third-harmonic generation in isotropic media by focused pulses

For focused pulses of light in isotropic nonlinear media, third-harmonic generation can be strongly affected by group-velocity mismatch between the fundamental and third-harmonic. There is a characteristic time determined by the group-velocity mismatch and the Rayleigh range of the focused pulse. The dynamics depend on two dimensionless quantities, namely the ratio of the characteristic time to the pulse duration and the phase-velocity mismatch times the Rayleigh range. Pulses shorter than the characteristic time have physics described by simple analytic formulas. Pulses near the characteristic time have an intermediate behavior given by an explicit but more complicated formula. Pulses longer than the characteristic time tend to the continuous-wave case