SPEEDUPtrademark ion exchange column model
Description
A transient model to describe the process of loading a solute onto the granular fixed bed in an ion exchange (IX) column has been developed using the SpeedUptrademark software package. SpeedUp offers the advantage of smooth integration into other existing SpeedUp flowsheet models. The mathematical algorithm of a porous particle diffusion model was adopted to account for convection, axial dispersion, film mass transfer, and pore diffusion. The method of orthogonal collocation on finite elements was employed to solve the governing transport equations. The model allows the use of a non-linear Langmuir isotherm based on an effective binary ionic exchange process. The SpeedUp column model was tested by comparing to the analytical solutions of three transport problems from the ion exchange literature. In addition, a sample calculation of a train of three crystalline silicotitanate (CST) IX columns in series was made using both the SpeedUp model and Purdue University's VERSE-LC code. All test cases showed excellent agreement between the SpeedUp model results and the test data. The model can be readily used for SuperLigtrademark ion exchange resins, once the experimental data are complete
Availability note (English)
Available from INIS in electronic form; Also available from OSTI as DE00752138; PURL: https://www.osti.gov/servlets/purl/752138-Oyx9zf/webviewable/
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Additional details
Identifiers
Publishing Information
- Imprint Pagination
- 63 p.
- Report number
- WSRC-TR--99-00401
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 31042333
- Subject category
- S12: MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADSORPTION ISOTHERMS; COMPUTERIZED SIMULATION; EXTRACTION COLUMNS; ION EXCHANGE; ION EXCHANGE MATERIALS; LOADING; S CODES; SOLUTES
- Descriptors DEC
- COMPUTER CODES; EQUIPMENT; EXTRACTION APPARATUSES; ISOTHERMS; MATERIALS; MATERIALS HANDLING; SEPARATION EQUIPMENT; SIMULATION
Optional Information
- Contract/Grant/Project number
- AC09-96SR18500
- Funding organization
- US Department of Energy (United States)