Published October 1977 | Version v1
Journal article Metadata-only

An ESR investigation of the vanadium pentoxide-water system illuminated in the solar spectrum range

Creators

  • 1. Kiel Univ. (Germany, F.R.). Inst. fuer Physikalische Chemie

Description

Photoreduction of vanadium (V) ions in aqueous solution is followed by ESR observation of the VO2+sub(aq) ions formed. In addition shortlived surface centers are detected at room temperature in illuminated V2O5-samples being suspended in water. These centers are tentatively related to the active species in the photoassisted electrolysis of water. (orig.)

Abstract (German)

Nach der Photoreduktion von Vanadium (V)-Ionen in waessriger Loesung werden die dabei gebildeten VO2+sub(aq)-Ionen mit Hilfe der ESR beobachtet. Ausserdem wurden kurzlebige Oberflaechenzentren bei Raumtemperatur in bestrahlten, wassersuspendierten V2O5-Proben nachgewiesen. Diese Zentren stehen in engem Zusammenhang mit den aktiven Zentren der photounterstuetzten Elektrolyse des Wassers. (orig.)

Additional details

Identifiers

DOI
10.1515/zna-1977-1012;

Publishing Information

Journal Title
Zeitschrift für Naturforschung A
Journal Volume
32
Journal Issue
10
Series
Z. Naturforsch., A.
Journal Page Range
1157-1160
ISSN
1865-7109

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
9374704
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
AQUEOUS SOLUTIONS; ELECTRON SPIN RESONANCE; PHOTON-ION COLLISIONS; VANADIUM OXIDES; VISIBLE RADIATION; VISIBLE SPECTRA; WATER
Descriptors DEC
CHALCOGENIDES; COLLISIONS; DISPERSIONS; ELECTROMAGNETIC RADIATION; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; ION COLLISIONS; MAGNETIC RESONANCE; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHOTON COLLISIONS; RADIATIONS; RESONANCE; SOLUTIONS; SPECTRA; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS

Optional Information

Notes
4 figs.; 12 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent