Published August 10, 2009 | Version v1
Journal article

FORMATION AND IDENTIFICATION OF INTERSTELLAR MOLECULE LINEAR C5H FROM PHOTOLYSIS OF METHANE DISPERSED IN SOLID NEON

  • 1. National Synchrotron Radiation Research Center, No. 101, Hsin-Ann Road, Hsinchu Science Park, Hsinchu 30076, Taiwan (China)
  • 2. Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China)
  • 3. Escuela de Quimica, Universidad de Costa Rica, Ciudad Universitaria Rodrigo Facio, San Pedro de Montes de Oca, San Jose 2060 (Costa Rica)

Description

Photolysis of methane dispersed (1/1000) in solid Ne at 3 K with vacuum-ultraviolet light from a synchrotron produced infrared absorption lines of several products, including new lines at 3319.3 and 1955.5 cm-1. Based on experiments with isotopic labeling and results of quantum-chemical calculations, these lines are assigned to the C-H stretching and C=C stretching modes, respectively, of interstellar molecule linear C5H radicals.

Availability note (English)

Available from http://dx.doi.org/10.1088/0004-637X/701/1/8

Additional details

Identifiers

Publishing Information

Journal Title
Astrophysical Journal
Journal Volume
701
Journal Issue
1
Journal Page Range
p. 8-11
ISSN
0004-637X
CODEN
ASJOAB

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41057019
Subject category
S79: ASTROPHYSICS, COSMOLOGY AND ASTRONOMY;
Descriptors DEI
ABSORPTION; CARBON; METHANE; NEON; PHOTOLYSIS; RADICALS; STARS; ULTRAVIOLET RADIATION
Descriptors DEC
ALKANES; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ELEMENTS; FLUIDS; GASES; HYDROCARBONS; NONMETALS; ORGANIC COMPOUNDS; PHOTOCHEMICAL REACTIONS; RADIATIONS; RARE GASES; SORPTION