Published October 2019
| Version v1
Journal article
Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate
Creators
- 1. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
- 2. Marshal V. I. Chuikov Moscow South-Eastern School (Russian Federation)
Description
In the interaction of norzooanemonin 1,3-dimethylimidazolium-4-carboxylate (1) with CuBr2, two types of crystals form: purple [Cu(L)2Br2][CuBr4][CuL4] (2) and light blue [CuL4][CuBr3] (3). In the reaction of 1 with CoCl2 in methanol, neutral complex Co(L)2Cl2 (4) forms. The thermal decomposition of complex 4 is studied. At the first stage of this decomposition, two equivalents of CO2 remove in a range 218–275 °C, and then a two-phase removal of two equivalents of L and the formation of CoCl2 occur.
Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Structural Chemistry
- Journal Volume
- 60
- Journal Issue
- 10
- Journal Page Range
- p. 1648-1654
- ISSN
- 0022-4766
- CODEN
- JSTCAM
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55025905
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBON DIOXIDE; COBALT CHLORIDES; COPPER BROMIDES; CRYSTALS; INTERACTIONS; METHANOL; PYROLYSIS; THERMAL GRAVIMETRIC ANALYSIS; ZWITTERIONIC COMPOUNDS
- Descriptors DEC
- ALCOHOLS; BROMIDES; BROMINE COMPOUNDS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COBALT COMPOUNDS; COBALT HALIDES; COPPER COMPOUNDS; COPPER HALIDES; DECOMPOSITION; GRAVIMETRIC ANALYSIS; HALIDES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; POLAR COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2019 Pleiades Publishing, Ltd.