Published May 2006 | Version v1
Journal article Metadata-only

First mesogenic derivative of boron difluoride β-diketonate

Creators

  • 1. KNTs RAN, Fiziko-Tekhnicheskij Inst. imeni E.K. Zavojskogo, Kazan' (Russian Federation)
  • 2. Kazanskij Gosudarstvennyj Tekhnologicheskij Univ, Kazan' (Russian Federation)

Description

Boron difluoride β-diketonate exhibiting liquid crystalline as well as photoluminescence properties was prepared for the first time as a promising material for creating supramolecular organized luminescent media. The complex was synthesized in a high yield (95%) by the reaction between 1-(dodecylhydroxyphenyl)-3-(4-tetradecylhydroxyphenyl)propane-1,3-dione and boron trifluoride etherate in toluene, and characterized by elemental analysis, 1H NMR, IR- and UV spectra

Abstract (Russian)

Впервые получен β-дикетонат дифторида бора, обладающий как жидкокристаллическими, так и фотолюминесцентными свойствами, - перспективный материал для создания надмолекулярно организованных люминесцентных сред. Комплекс получен с высоким выходом (95%) при взаимодействии 1-(4-додецилоксифенил)-3-(4-тетрадецилоксифенил)пропан-1,3-диона с эфиратом трифторида бора в толуоле и охарактеризован данными элементного анализа, ЯМР 1H, ИК- и УФ-спектроскопии

Additional details

Additional titles

Original title (Russian)
Первое мезогенное производное β-дикетоната дифторида бора

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
76
Journal Issue
5
Journal Page Range
p. 767-769
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37106684
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BORON COMPLEXES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; FLUORIDES; INFRARED SPECTRA; KETONES; LIQUID CRYSTALS; MOLECULAR STRUCTURE; NMR SPECTRA; PHOTOLUMINESCENCE; PROTONS; ULTRAVIOLET SPECTRA
Descriptors DEC
BARYONS; COMPLEXES; CRYSTALS; ELEMENTARY PARTICLES; EMISSION; FERMIONS; FLUIDS; FLUORINE COMPOUNDS; HADRONS; HALIDES; HALOGEN COMPOUNDS; LIQUIDS; LUMINESCENCE; NUCLEONS; ORGANIC COMPOUNDS; PHOTON EMISSION; SPECTRA; SYNTHESIS; YIELDS

Optional Information

Notes
22 refs., 1 fig.