Published 1975
| Version v1
Journal article
ESR investigations of T12+- and Pb3+-centres in alkali halides
Creators
- 1. Stuttgart Univ. (TH) (F.R. Germany). 3. Physikalisches Inst.
Description
Abstract The results of ESR investigations of Tl2+‐centres in NaCl, KCl, RbCl, KBr and of Pb3+‐centres in KCl are reported. The g‐factor and the heavy‐metal hyperfine (hf) constant as well as superhyperfine (shf) constants for the six nearest neighbour halogen nuclei are determined. The quadrupole interaction is analyzed in KBr:Tl2+. An interpretation of the shf‐ and the hf‐interaction is presented. Model calculations show that the complex formed by the centre ion and the six halogen ligands is strongly determined by covalent bonding.
Additional details
Identifiers
Publishing Information
- Journal Title
- physica status solidi (b)
- Journal Volume
- 68
- Journal Issue
- 1
- Series
- Phys. Status Solidi B.
- Journal Page Range
- 257-264
- ISSN
- 0370-1972
INIS
- Country of Publication
- German Democratic Republic
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 6202499
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- COVALENCE; ELECTRON SPIN RESONANCE; ELECTRONIC STRUCTURE; HYPERFINE STRUCTURE; LEAD IONS; MAGNETIC MOMENTS; POTASSIUM BROMIDES; POTASSIUM CHLORIDES; QUADRUPOLE MOMENTS; RUBIDIUM CHLORIDES; SODIUM CHLORIDES; THALLIUM IONS; WAVE FUNCTIONS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; BROMIDES; BROMINE COMPOUNDS; CHARGED PARTICLES; CHLORIDES; CHLORINE COMPOUNDS; FUNCTIONS; HALIDES; HALOGEN COMPOUNDS; IONS; MAGNETIC RESONANCE; POTASSIUM COMPOUNDS; RESONANCE; RUBIDIUM COMPOUNDS; SODIUM COMPOUNDS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent