Published January 1980
| Version v1
Journal article
Molecular orbital study of satellites in XPS spectra of BaTiO3 and TiO2
- 1. Lyon-1 Univ., 69 - Villeurbanne (France). Inst. de Physique Nucleaire
- 2. Lyon-1 Univ., 69 - Villeurbanne (France). Lab. d'Electronique et Physique du Solide
Description
XPS satellites of the main peaks (Ti 2psup(1/2), Ti 2psub(3/2), Ti 3s, Ti 3p, Ba 4d, etc.) are observed in both BaTiO3 and TiO2 spectra near 5.0, 6.2, 13.2 and 25 eV. The contributions of charge transfer transitions (shake-up) to the peaks at 6.2 eV and 13.2 eV are pointed out (1tsub(2g)-2tsub(2g) and 3sub(g)-4esub(g), respectively) while energy losses are involved in the four peaks. (orig.)
Additional details
Publishing Information
- Journal Title
- Chem. Phys. Lett.
- Journal Volume
- 69
- Journal Issue
- 2
- Series
- Chem. Phys. Lett.
- Journal Page Range
- 240-245
- ISSN
- 0009-2614
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- Netherlands
- INIS RN
- 12578871
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- BAND THEORY; BARIUM COMPOUNDS; CRYSTAL STRUCTURE; ELECTRONIC STRUCTURE; ENERGY LOSSES; ENERGY-LEVEL TRANSITIONS; EV RANGE 01-10; EV RANGE 10-100; MOLECULAR STRUCTURE; PHOTOELECTRON SPECTROSCOPY; SATELLITES; TITANIUM COMPOUNDS; TITANIUM OXIDES
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; CHALCOGENIDES; ELECTRON SPECTROSCOPY; ENERGY RANGE; EV RANGE; OXIDES; OXYGEN COMPOUNDS; SPECTROSCOPY; TRANSITION ELEMENT COMPOUNDS