Published 1977
| Version v1
Journal article
The rate of hydrolysis of zirconium in 1 M NaCl
Description
The rate of hydrolysis of zirconium chlorides in 1 M NaCl has been studied at 25, 50 and 750C. Total zirconium concentration was varied between 0.3 and 10 mM and hydroxyl number between 0 and 3. Rayleigh turbidities and pH values were measured as functions of time. Large variations in rate were observed, some solutions reaching a steady state in hours, others requiring years. The rate of change of turbidity is related analytically to (i) total zirconium concentration, (ii) hydroxyl number and (iii) temperature. (author)
Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Inorganic and Nuclear Chemistry
- Journal Volume
- 39
- Journal Issue
- 9
- Series
- J. Inorg. Nucl. Chem.
- Journal Page Range
- 1637-1640
- ISSN
- 0022-1902
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 8346120
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; HYDROLYSIS; MEDIUM TEMPERATURE; PH VALUE; SODIUM CHLORIDES; TEMPERATURE DEPENDENCE; TURBIDITY; ZIRCONIUM CHLORIDES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; DECOMPOSITION; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; KINETICS; MIXTURES; REACTION KINETICS; SODIUM COMPOUNDS; SOLUTIONS; SOLVOLYSIS; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent