Published 1982
| Version v1
Journal article
Electrode processes during deposition of uranous-uranic oxide from molten salt electrolytes
Creators
Description
Processes during cathodic deposition and anodic dissolution of uranous-uranic oxide from molten salt media have been studied in the temperature range 723-1D63 K both in inert gas atmosphere and in the air using voltammetric and chronopotentiometric methods. Interaction of mono-, di- and chlorouranates with molten chlorides of alkali metals has been studied. It is shown that two types of ions are present in solutions: UO3Cl- and UO22+. A scheme of electrochemical separation of uranous-uranic oxide is suggested: UO22++2UO3Cl-+2e reversible UO3O8+2Cl-
Additional details
Additional titles
- Original title (Russian)
- Электродные процессы при осаждении закиси-окиси урана из расплавленных солевых электролитов
Publishing Information
- Journal Title
- Radiokhimiya
- Journal Volume
- 24
- Journal Issue
- 2
- Series
- Radiokhimiya.
- Journal Page Range
- 164-167
- ISSN
- 0033-8311
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 14741052
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AIR; ALKALI METAL COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHLORIDES; ELECTROLYSIS; ELECTROLYTES; HIGH TEMPERATURE; INERT ATMOSPHERE; MOLTEN SALTS; REDUCTION; URANIUM COMPOUNDS; VERY HIGH TEMPERATURE
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; CONTROLLED ATMOSPHERES; FLUIDS; GASES; HALIDES; HALOGEN COMPOUNDS; KINETICS; REACTION KINETICS; SALTS
Optional Information
- Notes
- For English translation see the journal Soviet Radiochemistry (USA).