Published 1976 | Version v1
Journal article Metadata-only

Tertiary phosphine complexes of rhenium: a spectroscopic study

Creators

  • 1. Canterbury Univ., Christchurch (New Zealand)

Description

Complexes of the type ReOX3L2, ReNX2L3, ReX3(NO)L2 and ReX2(NO)L3 have been studied using, UV visible, IR and H1, C13 NMR spectroscopy. (X is a halogen, Cl, Br, I and L is a tertiary phosphine Et3P and Et2PhP). Evidence obtained on the blue cis isomer ReOCl3L2 suggests that the halogens are arranged on a face of the octahedral complex. Assignments of ν(Re-X) and ν(Re-P) vibrations have been made. Three complexes of technetium, [TcCl4(Ph3P)2], [TcCl3(Et2PhP)3] and [TcCl3(NO)(Et2PhP)2] have been isolated. (author)

Additional details

Identifiers

DOI
10.1016/0022-1902(76)80200-x;

Publishing Information

Journal Title
Journal of Inorganic and Nuclear Chemistry
Journal Volume
38
Journal Issue
12
Series
J. Inorg. Nucl. Chem.
Journal Page Range
2231-2237
ISSN
0022-1902

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
8295288
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
INFRARED SPECTRA; ISOMERS; LIGANDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHINES; RHENIUM COMPLEXES; STEREOCHEMISTRY; TECHNETIUM COMPLEXES; ULTRAVIOLET SPECTRA; VISIBLE SPECTRA
Descriptors DEC
COMPLEXES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; RESONANCE; SPECTRA; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
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