Published January 1979
| Version v1
Journal article
Nuclear quadrupole resonance 35Cl in the complexes of the 5 group element pentafluorides with trifluoride and pentafluoride of chlorine
- 1. AN SSSR, Moscow. Inst. Metallurgii
Description
The following complexes are investigated on 35Cl at 77 K by the NQR method: ClF5xnSbF5 (n=1, 2, 4), ClF5xTaF5, ClF3xnSbF5 (n=1, 2, 4), ClF3xMF5 (M=As,Nb,Ta), ClF5 and CsClF4. The order of the increase of the MF5 acseptor ability is established according the 35Cl NQR spectra. The correlation dependences in ClF3xMF5 complexes are found between ν(35Cl) and the electronegativity difference of F and M, and also between ν(35Cl) and the MF5 formation heats. Calculated are the population of valent 3p-orbitals of chlorium atoms in the ClF3xMF5 complexes, and in ClF3, ClF and CsClF4 as well
Additional details
Additional titles
- Original title (Russian)
- Ядерный квадрупольный разонанс
Publishing Information
- Journal Title
- Zh. Fiz. Khim.
- Journal Volume
- 53
- Journal Issue
- 1
- Series
- Zh. Fiz. Khim.
- Journal Page Range
- 160-166
- ISSN
- 0044-4537
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 10486626
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANTIMONY FLUORIDES; ARSENIC FLUORIDES; CESIUM CHLORIDES; CHLORINE FLUORIDES; CHLORINE 35; CORRELATIONS; FORMATION HEAT; LOW TEMPERATURE; NIOBIUM COMPLEXES; NUCLEAR QUADRUPOLE RESONANCE; SPECTRA; TANTALUM COMPLEXES; VALENCE
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ANTIMONY COMPOUNDS; ARSENIC COMPOUNDS; CESIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; CHLORINE ISOTOPES; COMPLEXES; ENTHALPY; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; PHYSICAL PROPERTIES; REACTION HEAT; RESONANCE; STABLE ISOTOPES; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- For English translation see the journal Russian Journal of Physical Chemistry (UK).