Published 1983 | Version v1
Miscellaneous Open

Mechanism of water oxidation by trivalent ruthenium trisdipyridyl complex

Creators

  • 1. AN SSSR, Chernogolovka. Otdelenie Inst. Khimicheskoj Fiziki

Description

Results of kinetic investigation of water oxidation reaction with photogenerated single-electron oxidizer-trisdipyridyl complex of Ru(3) are presented. CoCl2x6H2O within the concentration range of [Co2+]0=5x10-7 - 5x10-5 M was used as a reaction catalyst. The method of stopped flow with spectrophotometric recording was used in order to control the reaction kinetics

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Additional details

Additional titles

Original title (Russian)
Механизм реакции окисления воды трисдипиридильным комплексом трехвалентного рутения

Publishing Information

Imprint Title
6. Soviet-Franch seminar on catalysis
Journal Page Range
p. 20-23.
Report number
INIS-SU--300

Conference

Title
6. Soviet-French seminar on catalysis.
Dates
1983.
Place
Moscow (USSR).

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
16044590
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BIPYRIDINES; CATALYSIS; CATALYSTS; CHEMICAL REACTION KINETICS; COBALT CHLORIDES; COORDINATION VALENCES; HYDRATES; OXIDATION; OXIDIZERS; QUANTITY RATIO; RUTHENIUM COMPLEXES; WATER
Descriptors DEC
AZINES; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COBALT COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PYRIDINES; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; VALENCE

Optional Information

Notes
3 figs. Imprint:6. Sovetsko-Frantsuzskij seminar po katalizu.;Sbornik dokladov.