Published October 1986 | Version v1
Journal article

Solid solutions based on CdCr2Se4 with complex cation substitution

  • 1. AN SSSR, Sverdlovsk. Inst. Khimii

Description

The synthesis of solid solutions of Cd1-xMnxCr2Se4, CdCr2-xVxSe4 and Cd1-xMnxCr2-yVySe4 type is performed. The specimens are prepared by solid-phase synthesis. Established is the possibility of formation of solid solutions based on CdCr2Se4 with complex cation substitution in the compositions region: 0 ≤ x ≤ 0.4, for Cd1-xMnxCr2Se4, 0 ≤ x ≤ 0.3 for CdCr2-xVxSe4 and 0 ≤ x, y ≤ 0.2 for Cd1-xMnxCr2-yVySe4. Manganese ions isomorphously substitute cadmium ions in tetrahedral positions, whereas vanadium ions are distributed along cadmium and chromium sublattices

Additional details

Additional titles

Original title (Russian)
Твердые растворы на основе CdCr

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Neorg. Mater.
Journal Volume
22
Journal Issue
10
Series
Izv. Akad. Nauk SSSR, Neorg. Mater.
Journal Page Range
1635-1637
ISSN
0002-337X
CODEN
IVNMA

Optional Information

Notes
For English translation see the journal Inorganic Materials (USA).