Corrosion Inhibition Effect of N, N-diphenylthiourea on the Electrochemical Characteristics of Mild steel in Dilute Acidic Environments
- 1. Covenant Univ., Ota (Nigeria). Dept. of Mechnical Engineering
- 2. Tshwane Univ. of Technology, Pretoria (South Africa). Dept. of Chemical Metallurgical and Materials Engineering
- 3. Tshwane Univ. of Technology, Pretoria (South Africa). Dept. of Civil Engineering
Description
The electrochemical corrosion behaviour of n, n'-diphenylthiourea on the surface properties mild steel in attenuated sulphuric and hydrochloric acids (3M concentration) contaminated with 3.5 percent recrystallized sodium chloride at ambient temperatures was examined through weight loss analysis, open circuit potential monitoring and potentiodynamic polarization. The surface morphology of the samples was analyzed with scanning electron microscopy and x-ray diffractometry. Statistical analysis of the results was done with aid of ANOVA software to assess their statistical relevance. Results show the thiourea derivative performed more excellently in sulphuric than hydrochloric acid based on inhibition efficiency values. Observations from SEM/XRD image and data further confirm the results of experimental data. Statistical derivations reveal the overwhelming influence of exposure time on inhibition performance compared to concentration of the organic compound. (author)
Additional details
Publishing Information
- Journal Title
- Journal of the Chemical Society of Pakistan
- Journal Volume
- 38
- Journal Issue
- 2
- Journal Page Range
- p. 222-233
- ISSN
- 0253-5106
INIS
- Country of Publication
- Pakistan
- Country of Input or Organization
- Pakistan
- INIS RN
- 48009409
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADSORPTION; CORROSION INHIBITORS; MITIGATION; STEELS; SULFURIC ACID; THIOUREAS; X-RAY DIFFRACTION
- Descriptors DEC
- ALLOYS; CARBON ADDITIONS; CARBONIC ACID DERIVATIVES; COHERENT SCATTERING; DIFFRACTION; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IRON ALLOYS; IRON BASE ALLOYS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; SCATTERING; SORPTION; SULFUR COMPOUNDS; TRANSITION ELEMENT ALLOYS