Published 1978
| Version v1
Journal article
Recoil tritium reactions with CH3SiD3: pressure dependent yields
Description
The T + CH3SiD3 system has been studied to evaluate the effect of reactant pressure on parent-T yield. The substitution yields for C-H and Si-D bonds have been found to be in the ratio 1:1.7. The decomposition rate of the excited parent-T has been calculated on the basis of the above ratio and compared with experimental yields at low pressure. Hypotheses to explain the discrepancy between calculated and experimental values are discussed. (author)
Additional details
Identifiers
- DOI
- 10.1039/f19787400818;
Publishing Information
- Journal Title
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Journal Volume
- 74
- Journal Issue
- 0
- Series
- J. Chem. Soc. (London), Faraday Trans., I.
- Journal Page Range
- 818
- ISSN
- 0300-9599
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 9397634
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ALKANES; CHEMICAL BONDS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DEUTERIUM COMPOUNDS; HOT ATOM CHEMISTRY; PRESSURE DEPENDENCE; RECOILS; SCAVENGING; SILANES; TRITIUM; TRITIUM COMPOUNDS
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHEMISTRY; HYDRIDES; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; RADIOCHEMISTRY; RADIOISOTOPES; REACTION KINETICS; SILICON COMPOUNDS; YEARS LIVING RADIOISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent