Published July 1997 | Version v1
Journal article

Structure of tetrakis-pivaloyltrifluoroacetates of heavy rare earths and sodium. Crystal structure of NaEr(C8H10O2F3)4

  • 1. Inst. Neorganicheskoj Khimii SO RAN, Novosibirsk (Russian Federation)

Description

Roentgenostructural study of a representative isostructural series of pivaloyltrifluoacetates of heavy earths (Gd-Lu) and sodium - NaEr(C8H10O2F3)4: a=13.114(1), c=21.004(9) A, V=3128A, Z=3, sp.gr P31 is series contain [Ln(pta)4]- and complex anion Na+ cation. Impact of Na cation on ion stereochemistry is established. Interrelation of the structure bond with the volatility of the compound is discussed

Additional details

Additional titles

Original title (Russian)
Строение тетракис-пивалоилтрифторацетонатов тяжелых RZEh и натрия. Кристаллическая структура NaEr(C

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
38
Journal Issue
4
Journal Page Range
p. 762-774
ISSN
0136-7463
CODEN
ZSTKAI

Optional Information

Notes
26 refs.; 7 tabs.; 4 figs.