Published February 1987 | Version v1
Journal article

Correlations relative to alkali metal halides melting

  • 1. AN SSSR, Sverdlovsk. Ural'skij Nauchnyj Tsentr

Description

Using as an example alkali metal halides, an approach to the description of ionic salt melting lines on the basis of monoparametric thermodynamic similarity is considered. A correlation between thermodynamic similarity parameter (c) of melting lines and reduced change in the volume (Δν-tilde) in the melting point at atmospheric pressure is detected. Using the linear diameter rule evaluations of the critical point parameters on liquid-vapour equilibrium line are made. Existence of correlation between asymptotic values (T → 0) of pressure on melting lines, as well as on spinodals of streched liquid, is shown

Additional details

Additional titles

Original title (Russian)
Корреляции, относящиеся к плавлению галогенидов щелочных металлов
Augmented title (English)
MX (M = Li-Rb, X = F-I)

Publishing Information

Journal Title
Zh. Fiz. Khim.
Journal Volume
61
Journal Issue
2
Series
Zh. Fiz. Khim.
Journal Page Range
344-347
ISSN
0044-4537
CODEN
ZFKHA

Optional Information

Notes
For English translation see the journal Russian Journal of Physical Chemistry (UK).