Published March 2018 | Version v1
Journal article

Measurements of bubble point pressure and saturated liquid density for ((R1234yf + R290))

  • 1. University of Chinese Academy of Sciences, Beijing 100039 (China)
  • 2. Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

Description

Highlights: • Bubble point pressure and saturated liquid density for R1234yf + R290 were measured. • Measurements were carried out by a compact single-sinker densimeter. • The bubble point pressure data were correlated by the PR equation of state. • The liquid density were reproduced by VNDS equation and modified Rackett equation. In this paper, bubble point pressures and saturated liquid densities of {2,3,3,3-Tetrafluoroprop-1-ene (R1234yf) + propane (R290)} binary mixtures were measured using a compact single-sinker densimeter. Measurements were carried out over temperatures from (255.048 to 300.135) K and mole fractions of R1234yf at (0.113, 0.217, 0.322, 0.422, 0.533, 0.625). The experimental standard uncertainties were estimated to be less than 5 mK for the temperature, 2 kPa for the pressure, 0.003 for the mole fraction and 0.02% for the density. The experimental bubble point pressures were correlated by the Peng-Robinson equation of state, while the experimental saturated liquid densities were represented with the VDNS and our modified Rackett equations. In addition, saturated liquid densities of azeotropy point at temperatures T = (253.150, 263.150, 273.150, 283.150 and 293.150) K were determined based on our previous and present work.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2017.10.016

Additional details

Identifiers

DOI
10.1016/j.jct.2017.10.016;
PII
S002196141730383X;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
118
Journal Page Range
p. 77-81
ISSN
0021-9614
CODEN
JCTDAF

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
53012896
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BINARY MIXTURES; DENSIMETERS; DENSITY; EQUATIONS OF STATE; LIQUIDS; PROPANE
Descriptors DEC
ALKANES; DISPERSIONS; EQUATIONS; FLUIDS; HYDROCARBONS; MEASURING INSTRUMENTS; MIXTURES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES

Optional Information

Copyright
Copyright (c) 2017 Elsevier Ltd.