Published January 21, 1982
| Version v1
Journal article
Detection and analysis of anisotropic TI2+ centers in glass
Description
A highly anisotropic T12+ center induced in soda silicate glasses by γ irradiation at 77 K has been detected by ESR. The parameters for the semioccupied molecular orbital were estimated through line-shape simulation of the hyperfine structure by using a newly developed solution to the spin Hamiltonian. Upon thermal annealing of the irradiated sample, the anisotropic T12+ center relaxed into a nearly isotropic one. This reflects a change in coordiation of T12+ from axially distorted to spherical symmetry
Additional details
Additional titles
- Augmented title (English)
- Gamma radiation
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 86
- Journal Issue
- 2
- Series
- J. Phys. Chem.
- Journal Page Range
- 161-164
- ISSN
- 0022-3654
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 13677416
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; GAMMA RADIATION; GLASS; HYPERFINE STRUCTURE; LOW TEMPERATURE; PHYSICAL RADIATION EFFECTS; SILICON OXIDES; SODIUM OXIDES; THALLIUM
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHALCOGENIDES; DATA; ELECTROMAGNETIC RADIATION; ELEMENTS; INFORMATION; IONIZING RADIATIONS; MAGNETIC RESONANCE; METALS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RESONANCE; SILICON COMPOUNDS; SODIUM COMPOUNDS