Magnetic structure of rare-earth dodecaborides
- 1. Hahn Meiner Institute, Glienicker Street 100, D-14109 Berlin (Germany)
- 2. Institute of Experimental Physics, Slovak Academy of Sciences, SK-04353 Kosice (Slovakia)
- 3. Institute for Problems of Material Science, NASU, UA-252680 Kiev (Ukraine)
Description
We have investigated the magnetic structure of HoB12, ErB12 and TmB12 by neutron diffraction on isotopically enriched single-crystalline samples. Results in zero field as well as in magnetic field up to 5T reveal modulated incommensurate magnetic structures in these compounds. The basic reflections can be indexed with q=(1/2+/-δ, 1/2+/-δ, 1/2+/-δ), where δ=0.035 both for HoB12 and TmB12 and with q=(3/2+/-δ, 1/2+/-δ, 1/2+/-δ), where δ=0.035, for ErB12. In an applied magnetic field, new phases are observed. The complex magnetic structure of these materials seems to result from the interplay between the RKKY and dipole-dipole interaction. The role of frustration due to the fcc symmetry of dodecaborides and the crystalline electric field effect is also considered
Additional details
Identifiers
- DOI
- 10.1016/j.jssc.2005.10.046;
- PII
- S0022-4596(05)00504-9;
Publishing Information
- Journal Title
- Journal of Solid State Chemistry
- Journal Volume
- 179
- Journal Issue
- 9
- Journal Page Range
- p. 2748-2750
- ISSN
- 0022-4596
- CODEN
- JSSCBI
Conference
- Title
- 15. international symposium on boron, borides and related compounds
- Dates
- 21-26 Aug 2005
- Place
- Hamburg (Germany)
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38067884
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ERBIUM BORIDES; FCC LATTICES; HOLMIUM BORIDES; MAGNETIC FIELDS; MONOCRYSTALS; NEUTRON DIFFRACTION; PHASE DIAGRAMS; THULIUM BORIDES
- Descriptors DEC
- BORIDES; BORON COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; CUBIC LATTICES; DIAGRAMS; DIFFRACTION; ERBIUM COMPOUNDS; HOLMIUM COMPOUNDS; INFORMATION; RARE EARTH COMPOUNDS; SCATTERING; THULIUM COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.