Published September 2006 | Version v1
Journal article

Magnetic structure of rare-earth dodecaborides

  • 1. Hahn Meiner Institute, Glienicker Street 100, D-14109 Berlin (Germany)
  • 2. Institute of Experimental Physics, Slovak Academy of Sciences, SK-04353 Kosice (Slovakia)
  • 3. Institute for Problems of Material Science, NASU, UA-252680 Kiev (Ukraine)

Description

We have investigated the magnetic structure of HoB12, ErB12 and TmB12 by neutron diffraction on isotopically enriched single-crystalline samples. Results in zero field as well as in magnetic field up to 5T reveal modulated incommensurate magnetic structures in these compounds. The basic reflections can be indexed with q=(1/2+/-δ, 1/2+/-δ, 1/2+/-δ), where δ=0.035 both for HoB12 and TmB12 and with q=(3/2+/-δ, 1/2+/-δ, 1/2+/-δ), where δ=0.035, for ErB12. In an applied magnetic field, new phases are observed. The complex magnetic structure of these materials seems to result from the interplay between the RKKY and dipole-dipole interaction. The role of frustration due to the fcc symmetry of dodecaborides and the crystalline electric field effect is also considered

Additional details

Identifiers

DOI
10.1016/j.jssc.2005.10.046;
PII
S0022-4596(05)00504-9;

Publishing Information

Journal Title
Journal of Solid State Chemistry
Journal Volume
179
Journal Issue
9
Journal Page Range
p. 2748-2750
ISSN
0022-4596
CODEN
JSSCBI

Conference

Title
15. international symposium on boron, borides and related compounds
Dates
21-26 Aug 2005
Place
Hamburg (Germany)

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38067884
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ERBIUM BORIDES; FCC LATTICES; HOLMIUM BORIDES; MAGNETIC FIELDS; MONOCRYSTALS; NEUTRON DIFFRACTION; PHASE DIAGRAMS; THULIUM BORIDES
Descriptors DEC
BORIDES; BORON COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; CUBIC LATTICES; DIAGRAMS; DIFFRACTION; ERBIUM COMPOUNDS; HOLMIUM COMPOUNDS; INFORMATION; RARE EARTH COMPOUNDS; SCATTERING; THULIUM COMPOUNDS

Optional Information

Copyright
Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.