Enhanced alignment of Mn12-acetate micro-crystals
Creators
- 1. Department of Physics, Texas A and M University, College Station, TX 77843- 4242 (United States)
- 2. Department of Chemistry, Texas A and M University, College Station, TX 77842-3012 (United States)
Description
A dilute Mn12-acetate suspension composed of microscopic single crystals and single molecules in isopropanol was used for magnetic studies of Mn12-acetate single molecule magnets. We observed magnetic properties of the frozen Mn12-acetate suspension similar to large single crystals, specifically several sharp steps in the low-temperature hysteresis loop, indicating significantly enhanced alignment as compared to prior studies of micro-crystals. The greater the external magnetic field during alignment, the sharper the steps were in the low-temperature hysteresis loops, indicating that this method can be used for continuous control of alignment. A magnetic field of ∼0.5 T was sufficient to align the micro-crystals in the organic solvent to a degree previously observed only in much larger single crystals
Additional details
Identifiers
- DOI
- 10.1016/j.jmmm.2006.09.034;
- PII
- S0304-8853(06)01128-0;
Publishing Information
- Journal Title
- Journal of Magnetism and Magnetic Materials
- Journal Volume
- 312
- Journal Issue
- 1
- Journal Page Range
- p. 205-209
- ISSN
- 0304-8853
- CODEN
- JMMMDC
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39030087
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ACETATES; HYSTERESIS; MAGNETIC FIELDS; MAGNETIC PROPERTIES; MAGNETS; MANGANESE COMPOUNDS; MONOCRYSTALS; ORGANIC SOLVENTS
- Descriptors DEC
- CARBOXYLIC ACID SALTS; CRYSTALS; EQUIPMENT; NONAQUEOUS SOLVENTS; PHYSICAL PROPERTIES; SOLVENTS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.