Published May 2007 | Version v1
Journal article

Enhanced alignment of Mn12-acetate micro-crystals

  • 1. Department of Physics, Texas A and M University, College Station, TX 77843- 4242 (United States)
  • 2. Department of Chemistry, Texas A and M University, College Station, TX 77842-3012 (United States)

Description

A dilute Mn12-acetate suspension composed of microscopic single crystals and single molecules in isopropanol was used for magnetic studies of Mn12-acetate single molecule magnets. We observed magnetic properties of the frozen Mn12-acetate suspension similar to large single crystals, specifically several sharp steps in the low-temperature hysteresis loop, indicating significantly enhanced alignment as compared to prior studies of micro-crystals. The greater the external magnetic field during alignment, the sharper the steps were in the low-temperature hysteresis loops, indicating that this method can be used for continuous control of alignment. A magnetic field of ∼0.5 T was sufficient to align the micro-crystals in the organic solvent to a degree previously observed only in much larger single crystals

Additional details

Identifiers

DOI
10.1016/j.jmmm.2006.09.034;
PII
S0304-8853(06)01128-0;

Publishing Information

Journal Title
Journal of Magnetism and Magnetic Materials
Journal Volume
312
Journal Issue
1
Journal Page Range
p. 205-209
ISSN
0304-8853
CODEN
JMMMDC

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
39030087
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ACETATES; HYSTERESIS; MAGNETIC FIELDS; MAGNETIC PROPERTIES; MAGNETS; MANGANESE COMPOUNDS; MONOCRYSTALS; ORGANIC SOLVENTS
Descriptors DEC
CARBOXYLIC ACID SALTS; CRYSTALS; EQUIPMENT; NONAQUEOUS SOLVENTS; PHYSICAL PROPERTIES; SOLVENTS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.