Published October 7, 1991
| Version v1
Journal article
Effects of ionizing radiation on cyanamide and dimethylcyanamide
- 1. Leicester Univ. (United Kingdom). Dept. of Chemistry
Description
Irradiation of the pure title compounds and a range of dilute solid solutions produces a range of matrix-isolated radicals, identified by their EPR spectra. These include electron-loss centres, HNradicalCN and (Me2NradicalCN)+,and electron capture centres HNC(H)N.- and Me2N.. The former is a tautomer of the parent anion and the latter is formed by loss of CN-. In aqueous alkali glasses, the radical anion .N2CO3- is thought to be formed by addition of O.- to CN22-. (author)
Additional details
Publishing Information
- Journal Title
- Journal of the Chemical Society. Faraday Transactions
- Journal Volume
- 87
- Journal Issue
- 19
- Series
- J. Chem. Soc., Faraday Trans.
- Journal Page Range
- 3129-3136
- ISSN
- 0956-5000
- CODEN
- JCFTE
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 23014154
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL RADIATION EFFECTS; CYANAMIDES; ELECTRON LOSS; ELECTRON SPECTRA; GAMMA RADIATION; IRRADIATION; MOLECULAR STRUCTURE; RADICALS; TEMPERATURE RANGE 0065-0273 K
- Descriptors DEC
- CARBONIC ACID DERIVATIVES; ELECTROMAGNETIC RADIATION; IONIZING RADIATIONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; SPECTRA; TEMPERATURE RANGE