Published July 1995
| Version v1
Journal article
Influence of the outerspherical cations nature on the anion sublattice dynamics in compounds MM'AF6 according to 19F NMR data
- 1. AN SSSR, Vladivostok (Russian Federation). Inst. Khimii
Description
Dynamics of octahedral ions in MM'AF6 crystal compounds (M, M' = Li, Na, K, Rb, Cs; A = Ge, Ti) was considered in 115-500 K range. Types of internal motions of complex ions were determined and their activation energy was evaluated. Phase transformation of the first kind was revealed in LiRbTiF6 compound. 15 refs., 4 figs., 2 tabs
Additional details
Additional titles
- Original title (Russian)
- Влияние природы внешнесферных катионов на динамику анионной подрешетки в соединениях MMь1AF
Publishing Information
- Journal Title
- Zhurnal Strukturnoj Khimii
- Journal Volume
- 36
- Journal Issue
- 4
- Journal Page Range
- p. 697-702.
- ISSN
- 0136-7463
- CODEN
- ZSTKAI
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 27021426
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACTIVATION ENERGY; CESIUM COMPOUNDS; CRYSTAL STRUCTURE; CRYSTAL-PHASE TRANSFORMATIONS; FLUORIDES; GERMANIUM COMPLEXES; IONS; NMR SPECTRA; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0065-0273 K; TEMPERATURE RANGE 0273-0400 K; TEMPERATURE RANGE 0400-1000 K; TITANIUM COMPLEXES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHARGED PARTICLES; COMPLEXES; ENERGY; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; PHASE TRANSFORMATIONS; SPECTRA; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES