Published March 17, 2017 | Version v1
Journal article Metadata-only

Facile synthesis, structure elucidation, and magnetic properties of perovskite BaTb1-xBixO3

Creators

  • 1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing (China)
  • 2. College of Materials Science and Engineering, Guilin University of Technology, 541004, Guilin (China)
  • 3. Neutron Scattering Laboratory, Department of Nuclear Physics, China Institute of Atomic Energy, 102413, Beijing (China)

Description

A series of perovskite BaTb1-xBixO3 (0.0 ≤ x ≤ 0.25) solid solutions were synthesized by a typical solid-state method. Their structures were analyzed by a combination of X-ray diffraction, neutron diffraction, and selected-area electron diffraction. All of the materials crystalize in the P1 space group [a = 6.0582(1) Aa, b = 6.0473(1) Aa, c = 6.0693(1) Aa, α = 60.00(1) , β = 59.84(1) , γ = 60.06(1) for x = 0.0 at room temperature]. Magnetic measurements revealed that the magnetic-ordering temperature decreases with increasing Bi content in BaTb1-xBixO3; therefore, the presence of Bi decreases the magnetic interactions of Tb. Furthermore, the magnetic structure for BaTb1-xBixO3 has been fully described in space group P1. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/ejic.201601325

Additional details

Identifiers

DOI
10.1002/ejic.201601325;

Publishing Information

Journal Title
European Journal of Inorganic Chemistry (online)
Journal Volume
2017
Journal Issue
11
Journal Page Range
p. 1427-1434
ISSN
1099-0682
CODEN
EJICFO

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48070456
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BARIUM OXIDES; BISMUTH OXIDES; CRYSTAL STRUCTURE; ELECTRON DIFFRACTION; LATTICE PARAMETERS; MAGNETIC PROPERTIES; NEUTRON DIFFRACTION; PEROVSKITES; SOLID SOLUTIONS; SYNTHESIS; TERBIUM OXIDES; X-RAY DIFFRACTION
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; BISMUTH COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; DISPERSIONS; HOMOGENEOUS MIXTURES; MINERALS; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; SCATTERING; SOLUTIONS; TERBIUM COMPOUNDS

Optional Information

Notes
With 8 figs., 5 tabs.